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Persistent URL
http://purl.org/net/epubs/work/43282
Record Status
Checked
Record Id
43282
Title
The vibrational spectrum of indole
Contributors
J Tomkinson (STFC Rutherford Appleton Lab.)
,
J Riesz
,
P Meredith
,
SF Parker (STFC Rutherford Appleton Lab.)
Abstract
We have obtained the first inelastic neutron scattering spectra of indole, a fundamental component of many important bio-molecular systems, including the amino acid tryptophan. Spectra of the powder, aligned crystals, and 1, 3 deutero indole are given. This has provided the first clear comparison with ab-initio frequency calculations of indole in the vapour and crystal phases. Details are extracted and assignment schemes given. The use of these indole assignments as a basis for understanding the spectra of substituted indoles is demonstrated by the treatment of the INS spectra of the 5- and 6-fluoro indoles.
Organisation
CCLRC
,
ISIS
,
ISIS-TOSCA
Keywords
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Language
English (EN)
Type
Details
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Year
Journal Article
Chem Phys
345, no. 2-3 (2007): 230-238.
doi:10.1016/j.chemphys.2007.06.007
Indole-final-post-refs.doc
2007
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