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Persistent URL
http://purl.org/net/epubs/work/51078
Record Status
Checked
Record Id
51078
Title
Neutron spectroscopy and magnetic relaxation of the Mn6 nanomagnets
Contributors
S Carretta (Parma U.) (Pr.Au.)
,
T Guidi (STFC Rutherford Appleton Lab.)
,
P Santini (Parma U.)
,
G Amoretti (Parma U.)
,
O Pieper
,
B Lake
,
J van Slageren
,
F El Hallak
,
W Wernsdorfer
,
H Mutka
,
M Russina
,
CJ Milios
,
EK Brechin
Abstract
Inelastic neutron scattering has been used to determine the microscopic Hamiltonian describing two high-spin variants of the high-anisotropy Mn6 nanomagnet. The energy spectrum of both systems is characterized by the presence of several excited total-spin multiplets partially overlapping the S = 12 ground multiplet. This implies that the relaxation processes of these molecules are different from those occurring in prototype giant-spin nanomagnets. In particular, we show that both the height of the energy barrier and resonant tunnelling processes are greatly influenced by low-lying excited total-spin multiplets.
Organisation
ISIS
,
ISIS-ILL
,
STFC
Keywords
Physics
,
Molecular Nanomagnets
Funding Information
Related Research Object(s):
Licence Information:
Language
English (EN)
Type
Details
URI(s)
Local file(s)
Year
Journal Article
Polyhedron
28, no. 9-10 (2008): 1940-1944. Presented at: 11th International Conference on Molecule-Based Magnets (ICMM 2008), Florence, Italy, 21-24 Sept 2008.
doi:10.1016/j.poly.2008.11.009
2008
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